388613-52-3

Upstream product

• 19094-48-5 3,5-diiodobenzoic acid 
• 94-09-7 p-aminoethylbenzoate 
• 64-17-5 ethanol 
• 42860-25-3 3,5-diiodobenzoyl chloride 

Downstream Products

• 388613-53-4 3,5-bis-(3-trimethylsilanylethynyl-phenylethynyl)-benzoic acid ethyl ester 
• 19094-48-5 3,5-diiodobenzoic acid 
• 801983-46-0 3-(ethoxycarbonyl)-5-iodobenzoic acid 
• 388613-56-7 C₇₁H₅₄O₆Si₂ 
• 388613-55-6 C₄₅H₂₈Br₂O₆ 
• 388613-54-5 3,5-bis-(3-ethynyl-phenylethynyl)-benzoic acid ethyl ester 
• 681240-96-0 2-[2-(2-methoxy-ethoxy)-ethoxy]-ethyl 3,5-diiodobenzoate 
• 681240-97-1 (2-ethyl)-hexyl 3,5-diiodobenzoate 
• 42860-25-3 3,5-diiodobenzoyl chloride 
• 437707-58-9 ethyl 3,5-bis[(trimethylsilyl)ethynyl]benzoate 

Relevant academic research and scientific papers

Halogen-magnesium exchange on unprotected aromatic and heteroaromatic carboxylic acids

The magnesiation of halogenated aromatic and heteroaromatic carboxylic acids is accomplished by their treatment with MeMgCl in the presence of LiCl and subsequent reaction with i-PrMgCl·LiCl; the resulting double-magnesiated species react with a variety of electrophiles in up to 97% yield. The Royal Society of Chemistry.

Synthesis of medium-ring and iodinated biaryl compounds by organocuprate oxidation

(Chemical Equation Presented) A biaryl banquet! Biphenyls with four ortho substituents, heteroaromatic compounds, iodinated biaryls, and medium rings containing biaryls are all readily synthesized by organocuprate oxidation. The utility of this new methodology is illustrated by the efficient synthesis of the medium-ring core of sanguiin H-5 (see scheme).

Microwave-accelerated synthesis of lengthy and defect-free poly(m-phenyleneethynylene)s via AB′ and A2 + BB′ polycondensation routes

A novel microwave-assisted polycondensation protocol involving an in-situ activation/coupling scheme has been developed and applied to the preparation of lengthy poly(m-phenyleneethynylene)s without diyne defects via either AB′ or A2 + BB′ approaches.