38864-30-1

Usage

Type of compound

Phosphole derivative

Structure

Contains a phosphorus atom within a five-membered ring

Substituents

1-benzyl and 3,4-dimethyl groups

Application

Commonly used as a ligand in organometallic chemistry

Coordination

Can coordinate to transition metals to form stable complexes

Potential applications

Studied for use in materials science and as a building block for the synthesis of other organic compounds

Unique properties

Its structure and reactivity make it a valuable tool in various chemical research and industrial processes

Upstream product

• 38906-68-2 1-benzyl-1-bromo-3,4-dimethyl-2,5-dihydro-1H-phospholium; bromide 
• 100-39-0 benzyl bromide 
• 30540-36-4 3,4-dimethyl-1-phenylphosphole 
• 28273-33-8 1-bromo-3,4-dimethyl-Δ³-phospholen 

Downstream Products

• 38864-31-2 1,1-dibenzyl-3,4-dimethyl-1H-phospholium; bromide 
• 109827-20-5 2-tert-Butyl-4,5-dimethyl-λ³-phosphinin 
• 72553-94-7 4,5-dimethyl-2-phenylphosphinidine 
• 72553-93-6 1-benzyl-3,4-dimethyl-6-phenyl-1,2-dihydro-phosphinine 1-sulfide 
• 86421-45-6 trans-dichlorodicarbonylbis(1-benzyl-3,4-dimethylphosphole)ruthenium(II) 
• 86421-48-9 cis-dichlorotetrakis(1-benzyl-3,4-di-methylphosphole)ruthenium(II) 
• 86470-40-8 trans-dichlorotetrakis(1-benzyl-3,4-di-methylphosphole)ruthenium(II) 
• 72402-84-7 cis-dichlorobis(1-benzyl-3,4-trimethylphosphole)palladium(II) 
• 1609653-07-7 C₂₇H₃₇O₃P 
• 1609653-07-7 C₂₇H₃₇O₃P 
• 1609652-86-9 C₂₇H₃₇O₃PS 
• 68670-60-0 1-benzyl-1,3,4-trimethyl-1H-phospholium; iodide 
• 93633-48-8 C₁₅H₂₇N₂P 
• 68670-62-2 1-benzyl-4-methyl-3-methylene-2,3-dihydro-1H-phosphole 1-oxide 

Relevant academic research and scientific papers

P-chiral phosphorus heterocycles: A straightforward synthesis

A straightforward synthesis of P-chiral polycyclic 7-phospha-norbornenes via an asymmetric Diels-Alder reaction is presented. The employed starting materials are cheap, easily accessible and of structural diversity facilitating a new flexible route towards differently functionalised P-chiral phosphanes. This journal is the Partner Organisations 2014.

An unconventional synthesis of dibromophosphines

Dibromophosphines, RPBr2, are obtained by reaction of tetrabromomethane with 7-substituted 7-phosphanorbornenes in toluene at ca. 100 °C. The phosphanorbornenes are obtained in situ by cycloaddition of N-phenylmaleimide with 1-substituted 3,4-d