389121-75-9

Upstream product

• 178458-05-4 5,6,7,9-tetra-O-benzyl-1,2,3-trideoxy-α-D-gluco-non-1-en-4-ulopyranose 
• 762-72-1 allyl-trimethyl-silane 
• 13096-62-3 (3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)methyl)tetrahydro-2H-pyran-2-one 
• 4291-69-4 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 

Downstream Products

• 213776-97-7 allyl (5,6,7,9-tetra-O-benzyl-1,2,3-trideoxy)-α-D-gluco-non-1-eno-4-ulopyranose 

Relevant academic research and scientific papers

Trimethylsilyl trifluoromethanesulfonate catalyzed nucleophilic substitution to give C- and N-glucopyranosides derived from d-glucopyranose

This paper describes the synthesis of C- and N-glucopyranosides via trimethylsilyl trifluoromethanesulfonate catalyzed nucleophilic substitution of glucopyranosides, derived from D-glucopyranose, with methyl, ethyl, n-butyl, allyl, benzyl, and phenyl grou

Facile synthesis of conjugated exo-glycals

Two efficient methods were explored for the synthesis of various conjugated exo-glycals: (i) by nucleophilic addition of sugar lactones with a subsequent dehydration, and (ii) by selenylation of C-glycosides with subsequent selenoxide elimination. These reactions occurred in a stereoselective manner to give exclusively or predominantly the (Z)-isomers of exo-glycals.