389587-30-8Relevant academic research and scientific papers
New and efficient synthesis of 6,11-dihydro-11-ethyl-5H-dibenz[b,e]azepine derivatives starting from N-benzylanilines via amino-Claisen and Friedel-Crafts methodologies
Palma, Alirio,Barajas, Jacqueline Jaimes,Kouznetsov, Vladimir V.,Stashenko, Elena,Bahsas, Ali,Amaro-Luis, Juan
, p. 2721 - 2724 (2004)
New and efficient synthesis of 6,11-dihydro-11-ethyl-5H-dibenz[b,e]azepine derivatives, using the key steps of BF3·OEt 2-catalyzed aromatic amino-Claisen rearrangement and the intramolecular alkene Friedel-Crafts alkylation, is reported.
Proline triflate catalysed Diels-Alder reaction in the synthesis of tetrahydroquinoline derivatives
Li, Jianjun,Li, Jia,Su, Weike
experimental part, p. 499 - 504 (2010/01/16)
Proline triflate was found to catalyse efficiently the one-pot synthesis of 2H-pyranotetrahydroquinolines from aryl imines, and 3,4-dihydro-2H-pyran with high stereoselectivity. The aryl imines were formed in situ from aromatic amines and arylaldehydes.
