389614-53-3

Basic information

• Product Name: PhI(ODNs)OH
• Synonyms: PhI(ODNs)OH;[Hydroxy-(2,4-dinitrobenzenesulfonyloxy)iodo] benzene
• CAS NO: 389614-53-3
• Molecular Formula: C₁₂H₉IN₂O₈S
• Molecular Weight: 468.17793
• Mol File: 389614-53-3.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: PhI(ODNs)OH(CAS DataBase Reference)
• NIST Chemistry Reference: PhI(ODNs)OH(389614-53-3)
• EPA Substance Registry System: PhI(ODNs)OH(389614-53-3)

Safety Data

• Hazardous Substances Data: 389614-53-3(Hazardous Substances Data)

Upstream product

• 591-50-4 iodobenzene 
• 89-02-1 2,4-dinitrobenzenesulfonic acid 
• 3240-34-4 [bis(acetoxy)iodo]benzene 

Downstream Products

• 518068-78-5 2,4-dinitro-benzenesulfonic acid 2-(4-chloro-phenyl)-1-methyl-2-oxo-ethyl ester 
• 389614-52-2 α-[(2,4-dinitrobenzene)sulfonyl]oxyacetophenone 
• 518068-74-1 2,4-dinitro-benzenesulfonic acid 2-oxo-2-p-tolyl-ethyl ester 
• 518068-80-9 2,4-dinitro-benzenesulfonic acid 2-oxo-cyclohexyl ester 
• 1253201-07-8 2-(5-fluoropyridin-2-yl)-2-oxoethyl 2,4-dinitrobenzenesulfonate 
• 518068-82-1 C₁₇H₁₄N₂O₁₀S 

Relevant articles and documents

CALPAIN MODULATORS AND THERAPEUTIC USES THEREOF

Disclosed herein are small molecule calpain modulator compositions, pharmaceutical compositions, the use and preparation thereof.

α-Sulfonyloxylation of 1,3-dicarbonyl compounds utilizing hypervalent iodine(iii) reagent: Construction of quaternary carbon center

An efficient method for direct α-sulfonyloxylation of various sterically hindered 1,3-dicarbonyl compounds has been developed under mild reaction conditions. The yields of desired products is up to 90% and a plausible mechanism was accordingly proposed.

Hypervalent iodine(iii) sulfonate mediated synthesis of quinoxalines in liquid peg-400

PEG-400[poly(ethylene glycol-400)] is used as a "green" recyclable solvent in the one-pot synthesis of quinoxalines by reaction with aryl ketones, hypervalent Iodine(III) Sulfonate, and o-phenylenediamines. Significant rate enhancements and improved yields have been observed.

Facile one-pot preparation of [hydroxy(sulfonyloxy)iodo]arenes from iodoarenes with MCPBA in the presence of sulfonic acids

Various [hydroxy(sulfonyloxy)iodo]arenes were simply and efficiently obtained in high yields from the reaction of iodoarenes and MCPBA in the presence of sulfonic acids in a small amount of chloroform at room temperature, through a one-pot procedure. Georg Thieme Verlag Stuttgart.

Efficient Conversion of Alkyl Aryl Ketones to Aromatic Carboxylic Acids

An efficient method for the conversion of alkyl aryl ketones to aromatic carboxylic acids has been developed based on initial formation of α-organosulfonyloxy ketones and their subsequent oxidation reactions by tetrabutylammonium periodate in one-pot conditions.