38968-47-7

Upstream product

• 38968-40-0 3,5-dimethyl-benzo[c]isoxazole 
• 108-24-7 acetic anhydride 
• 38968-41-1 1-(2-azido-5-methylphenyl)ethan-1-one 
• 69976-70-1 1-(5-methyl-2-nitrophenyl)-ethanone 
• 25428-06-2 2-amino-5-methyl-acetophenone 
• 103-89-9 4-Methylacetanilide 
• 506-96-7 Acetyl bromide 
• 21296-92-4 2,3,5-trimethyl-1H-indole 
• 38818-49-4 5-methyl-2-nitrobenzoyl chloride 

Downstream Products

• 73129-52-9 2'-chloro-5-methylacetophenone 

Relevant academic research and scientific papers

Auto-tandem PET and EnT photocatalysis by crude chlorophyll under visible light towards the oxidative functionalization of indoles

Chlorophyll is the most abundant photocatalytic pigment that enables plants to absorb solar energy and convert it to energy storage molecules. Herein, we report a tandem photocatalytic approach utilizing the natural pigment chlorophyll in crude form to achieve photoinduced electron transfer (PET) and energy transfer (EnT) towards the oxidative functionalization of indoles. Redox potentials, ESR, fluorescence quenching and UV experiments have evidenced the dual catalytic activity of chlorophyll. The highlight of the study is the auto-tandem photocatalytic role of chlorophyll to enable the green oxidation of indoles using molecular oxygen as the oxidant, water as the reaction medium, and photochemical energy from the visible region of the spectrum.

Oxidative cleavage reaction of substituted indoles catalyzed by plant cell cultures

We have developed a novel method for the oxidative cleavage of indole carbon double bonds in the presence of H2O2 using plant cell cultures as peroxidase. The oxidative method has some advantage, as features such as mild reactions, good yields, easy work-up and safety.