791102-86-8

Basic information

• Product Name: 2-[(2E,6E,8E)-5-Benzenesulfonyl-3,7-dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6,8-trienyl]-isoindole-1,3-dione
• Synonyms: 2-[(2E,6E,8E)-5-Benzenesulfonyl-3,7-dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6,8-trienyl]-isoindole-1,3-dione
• CAS NO: 791102-86-8
• Molecular Weight: 557.754
• Mol File: 791102-86-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2-[(2E,6E,8E)-5-Benzenesulfonyl-3,7-dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6,8-trienyl]-isoindole-1,3-dione(CAS DataBase Reference)
• NIST Chemistry Reference: 2-[(2E,6E,8E)-5-Benzenesulfonyl-3,7-dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6,8-trienyl]-isoindole-1,3-dione(791102-86-8)
• EPA Substance Registry System: 2-[(2E,6E,8E)-5-Benzenesulfonyl-3,7-dimethyl-9-(2,6,6-trimethyl-cyclohex-1-enyl)-nona-2,6,8-trienyl]-isoindole-1,3-dione(791102-86-8)

Safety Data

• Hazardous Substances Data: 791102-86-8(Hazardous Substances Data)

Upstream product

• 114506-04-6 -4-Brom-1-chlor-2-methyl-2-buten 
• 1074-82-4 potassium phtalimide 
• 38987-91-6 5-(2,6,6-trimethyl-cyclohex-1-enyl)-3-methyl-1-phenyl-sulphonyl-penta-2,4-diene 
• 791102-79-9 2-((E)-4-Chloro-3-methyl-but-2-enyl)-isoindole-1,3-dione 

Downstream Products

• 74193-18-3 retinyl benzamide 
• 43219-26-7 N-retinyl-phthalimide 

Relevant articles and documents

Highly Efficient and General Synthetic Method of Various Retinyl Ethers

Bromination of 4 by PBr3 under Cu(I) catalyst produces the ambidextrous allylic halide 5 regioselectively and stereoselectively. Hetero nucleophiles distinguish the allylic carbon containing Br from the one containing Cl in 5 to give the heteroatom-substituted C5 allylic chloride 3. The Julia olefination reaction with the C15 sulfone 2 provides diverse retinyl ethers 1.