3901-77-7Relevant academic research and scientific papers
Reaction of organylchlorosilanes with dimethyl sulfoxide in the presence of octamethyltrisiloxane
Basenko,Gebel',Boyarkina,Voronkov
, p. 882 - 884 (2007/10/03)
Dichloro(methyl)(vinyl)silane reacts with DMSO in the presence of octamethyltrisiloxane to form cyclooligomethyl(vinyl)siloxanes(MeViSiO) n (n = 3-6). The reaction involves disproportionation of octamethyltrisiloxane into hexamethyldisiloxane and decamethyltetrasiloxane. Along with the latter two products, insertion products of methyl vinyl silanone into both permethyloligosiloxanes were identified. Alkyltrichlorosilanes RSiCl3 (R = Me, Et) react with DMSO in the presence of octamethyltrisiloxane to form cyclic oligoalkyltrichlorosiloxanes (RClSiO) m (m = 3-6).
FEATURES OF INFLUENCE OF HCl ON HYDROLYTIC COPOLYCONDENSATION OF BIFUNCTIONAL ORGANOCHLOROSILANES WITH TRIMETHYLCHLOROSILANE
Kopylov, V. M.,Agashkov, S. P.,Sunkovich, G. V.,Prikhod'ko, P. L.
, p. 1257 - 1261 (2007/10/02)
The hydrogen chloride that is formed in the hydrolytic copolycondensation of R'RSiCl2 with Me3SiCl affects the composition of the reaction products only at cocentrations above 30-35percent, where it is responsible for splitting out the terminal trimethylsiloxy group.The stability of the terminal groups increases with increasing size of the substituents on the silicon atom in the R'RSiCl2.The total yield of Me3SiO(R'RSiO)mSiMe3 with m = 1-4 also increases with increasing size of the substituents on the silicon atom in the R'RSiCl2.The total yield of p with p = 3-5 increases with decreasing tendency of the R'RSiCl2 to form rings by hydrolytic polycondensation, and with increasing sensitivity of the terminal trimethylsiloxy group in the cocondensation products to the action of HCl and its activity with respect to the siloxane bond.
