3901-91-5

Upstream product

• 4031-57-6 (1RS,2RS,4RS)-p-menthane-1,2-diol 
• 4031-57-6 (1RS,2RS,4SR)-p-menthane-1,2-diol 
• 4031-57-6 (1RS,2SR,4RS)-p-menthane-1,2-diol 
• 4031-57-6 (1RS,2SR,4SR)-p-menthane-1,2-diol 
• 3792-53-8 2-methyl-5-(prop-1-en-2-yl)cyclohexanone 
• 99-82-1 Menthane 
• 4017-88-3 (+/-)-cis-caran-trans-4-ol 
• 61585-35-1 p-menth-1-ene 
• 10309-68-9 (+)-4-trans-isopropenyl-1-methylbicyclo<3.1.0>hexan-2-one 
• 499-75-2 carvacrol 
• 23733-68-8 p-menth-3-en-2-one 
• 99-49-0 Carvone 

Downstream Products

• 134178-39-5 3-ethyl-2,5-dimethylcyclohex-2-en-1-one 
• 499-69-4 5-isopropyl-2-methylcyclohexan-1-ol 
• 499-69-4 5-isoprpyl-2-methylcyclohexan-1-ol 
• 114662-41-8 3-(pyrrolidinomethyl)p-menthan-2-one hydrochloride 
• 69770-96-3 4-Isobutyl-2-methyl-cyclopentanone 
• 499-69-4 5-isopropyl-2-methylcyclohexan-1-ol 
• 499-69-4 5-isopropyl-2-methylcyclohexan-1-ol 
• 499-69-4 (+)-carvomenthol 

Relevant academic research and scientific papers

Highly Selective Hydrogenation of Aromatic Ketones and Phenols Enabled by Cyclic (Amino)(alkyl)carbene Rhodium Complexes

Air-stable Rh complexes ligated by strongly σ-donating cyclic (amino)(alkyl)carbenes (CAACs) show unique catalytic activity for the selective hydrogenation of aromatic ketones and phenols by reducing the aryl groups. The use of CAAC ligands is essential for achieving high selectivity and conversion. This method is characterized by its good compatibility with unsaturated ketones, esters, carboxylic acids, amides, and amino acids and is scalable without detriment to its efficiency.

PHOTOCHEMICAL TRANSFORMATIONS-IV. OXYFUNCTIONALIZATION OF SOME SATURATED HYDROCARBONS WITH HYDROXYL RADICALS

It is shown that hydroxylation of saturated hydrocarbons by hydrogen peroxide occurs under the influence of light.This reaction has been investigated on acyclic, monocyclic and bicyclic hydrocarbons.These reactions were also studied using performic acid as the source of hydroxyl radicals and results compared with those obtained with peracetic acid.As expected, the preferred attack was on tertiary centres, followed by secondary and then primary.

HYDROGENOLYSE EN PHASE LIQUIDE SUR Pd/C DES EPOXYDES DU CARVOMENTHENE ET DU LIMONENE

Hydrogenolysis over Pd/C of cis and trans epoxides of carvomenthene and limonene give a mixture of hydrocarbons, secondary and tertiary alcohols, and ketones in proportions dependent upon the nature of the starting material.In the limonene epoxides, the extracyclic double bond plays an important role in the opening of the oxirane ring through a common unsaturated tertiary alcohol intermediate by double bond migration, hydrogenation of which leads to the products.For the carvomenthene epoxides the results are similar to those found in the 4-t-butyl series with competition between cis addition and trans addition of hydrogen.The presence of the isopropenyl group leads to slower reaction rates in comparison with t-butyl analogues.