39027-69-5Relevant academic research and scientific papers
A New Synthesis of (+/-)-Calamenene
Vig, O. P.,Verma, N. K.,Sharma, M. L.
, p. 992 - 993 (2007/10/02)
Grignard reaction of p-tolylmagnesium bromide on 6-methylhept-5-en-2-one (II) yields 2-(p-tolyl)-hept-5-en-2-ol (III), which on hydrogenolysis with 10percent Pd/C in absolute ethanol furnishes the hydrocarbon (IV) in high yield.Hydroboration of IV, follow
Synthesis of (+/-)-2-Methyl-6-(4'-methylphenyl)-1-hepten-3-one and (+/-)-2-Methyl-6-(4'-methylphenyl)-3-heptanone
Vig, O. P.,Dua, D. M.,Gauba, Rita,Puri, S. K.
, p. 406 - 407 (2007/10/02)
Epoxidation of α-curcumene (III) followed by cleavage of the resulting 2,3-epoxy-2-methyl-6-(4'-methylphenyl)heptane (IV) with diisopropylamide affords the allylic carbinol (V).V on oxidation with Corey's reagent furnishes 2-methyl-6-(4'-methylphenyl)-1-h
