39039-48-0Relevant academic research and scientific papers
Regioselective synthesis of 1,4-disubstituted triazoles using bis[(L)prolinato-N,O]Zn complex as an efficient catalyst in water as a sole solvent
Kidwai, Mazaahir,Jain, Arti
experimental part, p. 620 - 625 (2011/10/18)
A concise, convenient and mild route for one-pot regioselective synthesis of N-aryl- and N-alkyltriazoles in water as a sole solvent is reported. The methodology involves a three-component reaction comprising aryl/alkyl-alkyne, sodium azide and aryl/alkyl
Study of the reactivity of nitriles towards diazomethane: synthesis and structural study of N-methyl-v-triazoles
Danoun, Saida,Baziard-Mouysset, Genevieve,Stigliani, Jean-Luc,Commenges, Gerard,Carpy, Alain,Payard, Marc
, p. 943 - 951 (2007/10/02)
In this work, we examined the effect of diazomethane on 12 nitriles.Five gave rise to three isomeric N-methyl-v-triazoles, which were isolated.Their structural features were established and, in one case, corroborated by X-ray analysis.A generalization of the structural attribution by 13C NMR is proposed.A study of the electronic distribution was carried out for a total 17 nitriles and helped establish a predictive criterion of their reactivity towards diazomethane. diazomethane / nitrile / v-triazole / electronic density
Heterocyclic-methylene-penems
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, (2008/06/13)
(5R) (Z)-6-(1-methyl,1,2,3-triazol-4-yl-methylene)-penem-3-carboxylic acid and its salts are provided in analytically pure crystalline form, and the salts in hydrated form, for example (5R) sodium (Z)-6-(1-methyl-1,2,3-triazol-4-yl-methylene)penem-3-carboxylate monohydrate.
