3910-15-4Relevant articles and documents
Unimolecular Photopolymerization of High-Emissive Materials on Cylindrical Self-Assemblies
Zhu, Liangliang,Li, Xin,Sanders, Samuel N.,?gren, Hans
, p. 5099 - 5105 (2015)
We report a novel self-assembly pathway from a bis(imidazolyl) diphenyl-diacetylene (DPDA) compound as a realization of self-templated photopolymerization with high polymerization degrees. The work takes advantage of a cylindrical self-assembly that stren
Method for synthesizing 1,3-butadiyne compound by catalyzing molecular oxygen to oxidize water phase by water-soluble transition metal complex
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Paragraph 0066; 0067; 0068; 0069, (2018/09/13)
The invention provides a method for synthesizing a 1,3-butadiyne compound by catalyzing molecular oxygen to oxidize a water phase by a water-soluble transition metal complex. A water-soluble metal complex formed by complexing a transition metal and a water-soluble ligand is a catalyst; in an oxygen or air environment, an alkynyl silanes compound or a terminated alkynes compound reacts in an alkaline water phase to generate the 1,3-butadiyne compound; and the reaction pressure is 0.01 to 0.5 MPa, the reaction temperature is 40 to 100 DEG C, and the reaction time is 4 to 24 hours. According to the method provided by the invention, the synthesis step is simple, the reaction conditions are mild, the operation is simple, convenient and feasible, and the product yield is 99 percent; furthermore,the method is applicable to a wide range of substrates, and a new concept is provided for synthesis of the conjugated 1,3-butadiyne compound; the reaction is performed in the water phase without adding other organic solvents; and the catalyst is high in catalysis activity and high in reaction efficiency, can be used for multiple times, produces a small number of products, and has a relatively good industrial application prospect.
Engineering topochemical polymerizations using block copolymer templates
Zhu, Liangliang,Tran, Helen,Beyer, Frederick L.,Walck, Scott D.,Li, Xin,?gren, Hans,Killops, Kato L.,Campos, Luis M.
supporting information, p. 13381 - 13387 (2015/03/30)
With the aim to achieve rapid and efficient topochemical polymerizations in the solid state, via solution-based processing of thin films, we report the integration of a diphenyldiacetylene monomer and a poly(styrene-b-acrylic acid) block copolymer templat