39110-03-7

Upstream product

• 7065-21-6 tetraphenyldibismuthine 
• 603-33-8 triphenylbismuthane 
• 7787-64-6 bismuth(III) iodide 

Downstream Products

• 41137-17-1 phenylbiphenyl-2,2'-ylenebismuthane 
• 76185-19-8 bismuth(III) quinolin-8-olate 
• 1239474-57-7 1-phenyl-3,6-bis(trimethylsilyl)dithienobismole 
• 1239474-59-9 1-phenyl-2,4-di(benzo[b]thieno)bismole 
• 1239474-58-8 1-phenyl-2,7-dimethyl-3,6-bis(trimethylsilyl)dithienobismole 
• 88473-11-4 PhBi(8-quinolinolato)2 
• 603-33-8 triphenylbismuthane 
• 219745-49-0 iodobis(quinolin-8-olato)bismuth(III) 
• 95825-92-6 iododiphenylbismuth(III) 
• 88473-26-1 PhBi(2-methyl-8-quinolinolato)2 
• 88635-81-8 1-phenyl-2,5-dimethylbismole 
• 137594-88-8 1-phenyl-2,5-bis(trimethylsilyl)-3,4-dimethylbismole 

Relevant academic research and scientific papers

Structural Studies on Phenyl Bismuth Halides and Halogenoanions

Structural studies by X-ray crystallography have been carried out for a range of phenyl bismuth halides and halogenoanions.The complexes 1 and 2 (thf = tetrahydrofuran) form onedimensional polymeric chains with a single asymme

REACTIVITY OF MOLECULES CONTAINING ELEMENT-ELEMENT BONDS. PART III. REDUCTION OF HALO-ORGANOMETALLICS OF ANTIMONY(III) AND BISMUTH(III); CRYSTAL AND MOLECULAR STRUCTURE OF CoCp2

Tetraphenyldibismuthine has been prepared by reducing BiPh2I with bis (cyclopentadienyl)-cobalt(II).CoCp2, the former being produced in situ in THF solution from BiPh3 and BiI3 (2:1 molar ratio) or from BiPh3 and I2; also, bis(pentamethylcyclopentadienyl)cobalt(II), CoCp2, reduces BiPh2Cl to Bi2Ph4 in THF solution.The bismuth(III) bromides Bi(p-tolyl)2Br or BiMe2Br have been reduced by CoCp2 to the corresponding dibismuthines, Bi2(p-tolyl)4 or Bi2Me4.Reduction by CoCp2 of the chloro derivatives of bismuth(III) and antimony(III), EPh2Cl produces E2Ph4 and the ionic CoCp2 complexes as by-products.The crystal and molecular structure of the antimony derivative CoCp2 was solved by X-ray diffraction methods.Crystal data: monoclinic, space group P21, a = 8.856(3), b = 16.245(5), c = 7.770(3) Angstroem, β = 109.67(5) deg, Z = 2, R = 0.0396.Similar to Bi2Ph4, Sb2Ph4 undergoes reactions across the element-element bond with p-benzoquinone and diazomethane to the corresponding insertion products (Ph2Sb)2O2C6H4 and (Ph2Sb)2CH2, respectively.