88473-11-4

Basic information

• Product Name: PhBi(8-quinolinolato)2
• Synonyms: PhBi(8-quinolinolato)2
• CAS NO: 88473-11-4
• Molecular Weight: 574.392
• Mol File: 88473-11-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: PhBi(8-quinolinolato)2(CAS DataBase Reference)
• NIST Chemistry Reference: PhBi(8-quinolinolato)2(88473-11-4)
• EPA Substance Registry System: PhBi(8-quinolinolato)2(88473-11-4)

Safety Data

• Hazardous Substances Data: 88473-11-4(Hazardous Substances Data)

Upstream product

• 2872-54-0 sodium 8-quinolinolate 
• 39110-03-7 diiodo(phenyl)bismuth(III) 
• 177574-84-4 tetrabutylammonium quinolin-8-olate 
• 95825-92-6 iododiphenylbismuth(III) 

Downstream Products

• 76185-19-8 bismuth(III) quinolin-8-olate 

Relevant articles and documents

Preparation and reactivity of some phenylbismuth(III) quinolin-8-olate derivatives

The bimetallics [PhBi(Ox)2(NaX)n] (Ox- = quinolin-8-olate: X = Cl, Br or I), containing variable amounts of sodium halides, have been prepared by reaction of PhBiX2 with Na(Ox) (mole ratio 1:2) or of Ph2BiX with Na(Ox) (mole ratio 1:1) in ethanol. A similar preparation has given [PhBi(MeOx)2(NaI)n] (MeOx- = 2-methylquinolin-8-olate). The bimetallics have been characterized by X-ray powder photography, f.a.b. mass spectrometry and 1H n.m.r. and electronic spectroscopy. Sodium halide-free PhBi(Ox)2 was obtained from the reaction of Ph2BiCl with Na(Ox) in the presence of 15-crown-5, or from treatment of PhBiI2 or Ph2BiI with NBu4(Ox). Reaction of equimolar amounts of PhBiI2 and Na(Ox) gives Bi(Ox)2I. which can also be obtained from BiI3 and Na(Ox) in a 1:1 or 1:2 stoichiometry. Treatment of PhBiI2 with M(Ox) (M = Na or K) in a 1:3 mole ratio yields [MPhBi(Ox)3] bimetallics, which appear to contain both chelating and unidentate Ox ligands from their electronic spectra.