39135-36-9Relevant articles and documents
Visible-light photocatalytic reduction of sulfonium salts as a source of aryl radicals
Donck, Simon,Baroudi, Abdulkader,Fensterbank, Louis,Goddard, Jean-Philippe,Ollivier, Cyril
, p. 1477 - 1482 (2013/06/27)
Triarylsulfonium salts are prompted to undergo efficient homolytic reduction by single electron transfer under mild photocatalytic conditions. The liberated aryl radical can then participate in carbon-carbon bond formation processes with allyl sulfones and activated olefins. Triarylsulfonium salts emerge as a valuable and alternative source of aryl radicals for synthesis. Copyright