39149-69-4

Upstream product

• 762-72-1 allyl-trimethyl-silane 

Downstream Products

• 132604-44-5 2-Acetyl-2-((Z)-2-benzenesulfonyl-1-bromomethyl-vinyl)-pent-4-enoic acid tert-butyl ester 
• 57428-67-8 6-Allyl-2-cyclohexenone 
• 134673-30-6 2-Acetyl-2-(3-oxo-propyl)-pent-4-enoic acid tert-butyl ester 
• 134673-27-1 1-Allyl-2-oxo-cyclohex-3-enecarboxylic acid tert-butyl ester 
• 132604-77-4 2-Allyl-3-<(phenylsulfonyl)methyl>-2-cyclopenten-1-one 
• 1432601-91-6 (R)-tert-butyl 2-(5,5-dimethyl-3-oxocyclohex-1-enyl)pent-4-enoate 
• 1432601-99-4 (R)-tert-butyl 2-((R)-4-methyl-3-oxocyclohex-1-enyl)pent-4-enoate 
• 1432601-69-8 (R)-tert-butyl 2-(3-oxocyclohex-1-enyl)pent-4-enoate 
• 1426657-75-1 tert-butyl 2-(4-methyl-3-oxocyclohex-1-enyl)pent-4-enoate 
• 1426657-45-5 tert-butyl 2-(3-oxocyclohex-1-enyl)pent-4-enoate 
• 84695-64-7 6-allyl-3-methyl-cyclohex-2-enone 
• 154779-09-6 3-<((p-Nitrophenyl)sulfonyl)oxy>-5-hexen-2-one 

Relevant academic research and scientific papers

Solvent-dependent chemoselectivities in additions of β-carbonyl imines to allyltrimethylsilane with CTAN

The oxidative coupling of β-carbonyl imines and allyltrimethylsilane with CTAN were investigated in CH3CN and CH2Cl 2. In CH3CN allylation products were obtained predominantly, while in CH2Cl2, dihydropyrrole products were obtained exclusively. Solvent-assisted nucleophilic cleavage of the intermediate β-silyl cation is proposed to play a role in the solvent-dependent chemoselectivity.