57428-67-8

Upstream product

• 930-68-7 cyclohexenone 
• 106-95-6 allyl bromide 
• 94-66-6 2-allylcyclohexan-1-one 
• 1121-66-0 2-Cyclohepten-1-one 
• 112587-04-9 (E)-1-nitrohexa-1,5-diene 
• 142-71-2 copper diacetate 
• 64-19-7 acetic acid 
• 39149-69-4 tert-butyl 2-acetyl-4-pentenoate 
• 107-02-8 acrolein 
• 112587-02-7 2-Allyl-5-chlorocyclohexanone oxime 

Downstream Products

• 94-66-6 2-allylcyclohexan-1-one 
• 1415503-61-5 2-allylcyclohexa-1,5-dien-1-yl 2-chloroacetate 

Relevant academic research and scientific papers

POLYCYCLIC CARBOGENIC MOLECULES AND USES THEREOF AS ANTI-CANCER AGENTS

Disclosed are new polycyclic carbogenic molecules and their methods of synthesis. The new polycyclic carbogenic molecules may be utilized in anti-cancer therapies. In particular, the polycyclic carbogenic molecules may be formulated as pharmaceutical comp

A strategy for the convergent and stereoselective assembly of polycyclic molecules

The stereoselective oxidative coupling of cyclic ketones via silyl bis-enol ethers followed by ring-closing metathesis is shown to be a general and powerful reaction sequence for the preparation of diverse polycyclic scaffolds from simple precursors. The

Hydrolytic enantioselective protonation of cyclic dienyl esters and a β-diketone with chiral phase-transfer catalysts

Hydrolytic enantioselective protonation of dienyl esters and a β-diketone catalyzed by phase-transfer catalysts are described. The latter reaction is the first example of an enantio-convergent retro-Claisen condensation. Corresponding various optically active α,β-unsaturated ketones having tertiary chiral centers adjacent to carbonyl groups were obtained in good to excellent yields and enantiomeric ratios (83-99%, up to 97.5:2.5 er).

Organocatalytic dynamic kinetic resolution via conjugate addition: Synthesis of chiral trans-2,5-dialkylcyclohexanones

A novel strategy of initiating an organocatalysed dynamic kinetic resolution (dr up to 99:1 and er up to 94:6) for the synthesis of chiral trans-2,5-dialkylcyclohexanones by an asymmetric conjugate addition of dimethyl malonate on to 6-substituted cyclohexenones is reported.

Mn(III)-based oxidative free-radical cyclizations of unsaturated ketones

Mn(III)-based oxidative free-radical cyclization of unsaturated ketones is a versatile synthetic procedure with broad applicability. For example, oxidation of cyclopentanone 1a with 2 equiv of Mn(OAc)3·2H2O and 1 equiv of Cu(OAc)sub

Intramolecular Cross-ring Enone-Alkene Photoannelation in 6-(ω-Alkenyl)-cyclohex-2-en-1-ones

The irradiation of some 6-(ω-alkenyl)-cyclohex-2-en-1-ones in micelles gave a carbonyl bridged intramolecular photoadduct but the reaction is restricted to enones tethered to an alkene by not more than a four-carbon chain.

A Novel Synthesis of Bicyclic Isoxazolines via Sequential Michael and Intramolecular 1,3-Dipolar Additions

Bicyclic isoxazolines are obtained in good yields by the titanium tetrachloride-mediated reaction of allylic stannanes with 1-nitroalkadienes.Titanium tetrachloride converts stannyl nitronates generated in the Michael addition step to nitrile oxide equiva