39150-04-4Relevant articles and documents
Novel synthesis method of clean and safe photoinitiator (2,4,6-trimethylbenzoyldiphenyl-diphenylphosphine oxide)
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Paragraph 0057; 0058, (2019/06/12)
The invention relates to the technical field of synthesis of photoinitiators, in particular to a novel synthesis method of a clean and safe photoinitiator (2,4,6-trimethylbenzoyldiphenyl-diphenylphosphine oxide). The method includes the steps of evenly mixing anhydrous alcohol with N-methylimidazole at the room temperature, raising the temperature to 30-50%, controlling the temperature, dropwise adding diphenylphosphine oxide, raising the temperature to 50-100 DEG C, conducting the constant-temperature reaction for 2-3 h, conducting standing and layering to take supernatant liquid for decompressing and distilling to obtain diphenyl alkoxylphosphine, making the diphenyl alkoxylphosphine start to react with 2,4,6-trimethylbenzoyldiphenyl chloride at the controlled temperature of 50 DEG C under the vacuum condition of -0.098 Mpa, raising the temperature by 10 DEG C every 20 minutes until the temperature is raised to 90 DEG C, conducting the constant-temperature reaction for 4-8 h, and adding 50% ethyl alcohol crystals to obtain a target product. The produced byproduct is subjected to vacuum removal and then enters a tail gas recovery system to be recovered through two stages of condensation. The synthesis method is simple in step, safe, clean, low in running cost and high in byproduct recovery rate.
