39152-66-4Relevant academic research and scientific papers
Reactions of tris(triphenylphosphine)platinum(0). II. Preparation and properties of boron trichloride and aluminum trimethyl adducts of platinum(0)
Durkin,Schram
, p. 1054 - 1059 (2008/10/08)
Treatment of [(C6H5)3P]3Pt with BCl3 affords [(C6H5)3P]3Pt·2BCl 3 whereas [(C6H5)3P]4Pt affords [(C6H5)3P]3Pt·2BCl 3 and (C6H5)3P·BCl3. Reaction of [(C6H5)3P]3Pt·2BCl 3 with pyridine (py) yields py·BCl3 while pyrolysis of the adduct affords benzene. Treatment of [(C6H5)3P]2Pt·SiF4 with BCl3 yields [(C6H5)3P]2Pt·BCl3 whereas reaction with [Al(CH3)3]2 affords a paramagnetic Pt species and mixed fluoromethylsilanes. Reaction of [(C6H5)3P]3Pt with [Al(CH3)3]2 results in the formation of [(C6H5)3P]2Pt·2Al(CH 3)3 which readily decomposes in solution to yield two weakly paramagnetic species. One radical is associated with Pt and the other with Al.
