39167-47-0Relevant articles and documents
Synthesis of 2-unsubstituted 1,3-selenazoles by cyclization of selenoformamide with α-bromocarbonyl compounds
Below, Harald,Pfeiffer, Wolf-Diethard,Geisler, Karlheinz,Saghyan, Ashot S.,Fischer, Christine,Langer, Peter
, p. 592 - 596 (2015/03/30)
2-Unsubstituted 1,3-selenazoles were prepared by cyclization of selenoformamide with α-bromoacetophenones. Parent 1,3-selenazole was prepared by cyclization of selenoformamide with α-bromoacetaldehyde.
SYNTHESES WITH DIKETO SELENIDES
Nakayama, Juzo,Shibuya, Masahiro,Ikuina, Yoji,Murai, Fumito,Hoshino, Masamatsu
, p. 149 - 156 (2007/10/02)
We report a) a modified synthesis of diketo selenides, b) preparation of 2,5-diacylselenophenes by condensation of diketoselenides with glyoxal, c) preparation of poly-substituted selenophenes by intramolecular reductive coupling reaction of diketo selenides with low-valent titanium reagent under controlled conditions (0 degC) followed by dehydratation of the resulting 3,4-dihydroxyselenolanes, and d) formation of 2,5-dihydroselenophenes and 1,3-dienes by treatment of diketo selenides with the low-valent titanium reagent in refluxing tetrahydrofuran.