391860-75-6

Upstream product

• 146934-02-3 2-N-Allyloxycarbonyl-2-amino-2-deoxy-D-glucopyranose 
• 1078691-95-8 (+)-D-glucosamine hydrochloride 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 107-18-6 allyl alcohol 

Downstream Products

• 1363462-00-3 C₄₉H₅₆N₂O₁₄ 
• 1363461-52-2 allyl 2-allyloxycarbonylamino-4-O-benzyl-2-deoxy-α-D-glucopyranoside 
• 1363461-89-5 allyl 2-allyloxycarbonylamino-4-O-benzyl-2-deoxy-3-O-(4-methoxyphenylmethyl)-α-D-glucopyranoside 
• 1363461-54-4 allyl 2-allyloxycarbonylamino-4-O-benzyl-6-O-[4,6-O-benzylidene-2-deoxy-3-O-(4-methoxyphenylmethyl)-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranosyl]-3-O-benzyloxycarbonyl-2-deoxy-α-D-glucopyranoside 
• 1363461-98-6 allyl 2-allyloxycarbonylamino-4-O-benzyl-6-O-[4,6-O-benzylidene-2-deoxy-3-O-(4-methoxyphenylmethyl)-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranosyl]-2-deoxy-α-D-glucopyranoside 
• 1363461-65-7 allyl 2-allyloxycarbonylamino-4-O-benzyl-6-O-[4-O-benzyl-2-deoxy-3-O-(4-methoxyphenylmethyl)-2-(2,2,2-trichloroethoxycarbonylamino)-β-D-glucopyranosyl]-3-O-benzyloxycarbonyl-2-deoxy-α-D-glucopyranoside 
• 1363461-87-3 allyl 2-allyloxycarbonylamino-4,6-O-benzylidene-2-deoxy-3-O-(4-methoxyphenylmethyl)-α-D-glucopyranoside 

Relevant academic research and scientific papers

TMSCl as a mild and effective source of acidic catalysis in Fischer glycosidation and use of propargyl glycoside for anomeric protection

Practical Fischer glycosidation was effected at room temperature or 60°C by using 5 to 10 equiv. of TMSCl. The anomeric propargyl group formed by this method was found to be a versatile new protecting group, being stable in neat TFA but readily cleaved by treatment with Co2(CO)8 and TFA in CH2Cl2 via the formation of an alkyne-Co complex.

Synthetic study of peptidoglycan partial structures. Synthesis of tetrasaccharide and octasaccharide fragments

Partial structures of peptidoglycan, a potent immunostimulating glycoconjugate of bacteria, were synthesized for precise biological studies. A key disaccharide glucosaminyl-β(1-4)-muramic acid was prepared by stereoselective glycosylation of a N-Troc (Tro