392292-98-7Relevant academic research and scientific papers
Investigations into the mechanism of activation and initiation of ethylene polymerization by bis(imino)pyridine cobalt catalysts: Synthesis, structures, and deuterium labeling studies
Humphries, Martin J.,Tellmann, Kilian P.,Gibson, Vernon C.,White, Andrew J. P.,Williams, David J.
, p. 2039 - 2050 (2008/10/09)
The activation of bis(imino)pyridine cobalt(II) precatalysts by MAO leads initially to a bis(imino)pyridine cobalt(I) cationic species with no cobalt-C(alkyl) bond into which insertion can occur. Mechanistic studies have shown that the initiation of polym
The nature of the active species in bis(imino)pyridyl cobalt ethylene polymerisation catalysts
Gibson, Vernon C.,Humphries, Martin J.,Tellmann, Kilian P.,Wass, Duncan F.,White, Andrew J. P.,Williams, David J.
, p. 2252 - 2253 (2020/09/03)
Studies on cobalt ethylene polymerisation catalysts bearing bis(imino)pyridine ligands strongly indicate that the activated species is not the anticipated cobalt(II) alkyl cation.
