39274-71-0Relevant academic research and scientific papers
Electrophilic addition of allylic carbocations to 2-cyclopropylidene-2- arylethanols: A strategy to 3-oxabicyclo[3.2.0]heptanes
Meng, Bo,Huang, Xian,Wu, Luling
, p. 2637 - 2650 (2013/10/21)
We have developed an electrophilic addition of allylic carbocations to 2-cyclopropylidene-2-arylethanols constructing carbon-carbon bonds with excellent regio- and stereoselectivities. The reaction affords 3-oxabicyclo[3.2.0]heptanes in moderate to good y
Electronic effects in the regioselectivity of nucleophilic attacks on cationic 1,3-diaryl-π-allylpalladium complexes
Prat,Ribas,Moreno-Manas
, p. 1695 - 1706 (2007/10/02)
Nucleophilic attacks on π-allylpalladium complexes derived from O2N-Ph-(CH-CH-CH)-Ph-X systems (X = 4-OMe and 4-Cl) occur preferentially at the allylic terminus remote from the electron-withdrawing group (NO2).
