39298-52-7

Basic information

• Product Name: [(E)-tetradec-11-enyl] acetate
• CAS NO: 39298-52-7
• Molecular Formula: C₁₆H₃₀O₂
• Molecular Weight: 254.4082
• Mol File: 39298-52-7.mol
• Article Data: 42

Chemical Properties

• Boiling Point: 316.2°Cat760mmHg
• Flash Point: 87.2°C
• Density: 0.878g/cm³
• CAS DataBase Reference: [(E)-tetradec-11-enyl] acetate(CAS DataBase Reference)
• NIST Chemistry Reference: [(E)-tetradec-11-enyl] acetate(39298-52-7)
• EPA Substance Registry System: [(E)-tetradec-11-enyl] acetate(39298-52-7)

Safety Data

• Hazardous Substances Data: 39298-52-7(Hazardous Substances Data)

Usage

General Description

[(E)-tetradec-11-enyl] acetate is a chemical compound that is also known as ethyl (E)-tetradec-11-enoate. It is a ester, which means it is formed from the reaction between acetic acid and (E)-tetradec-11-enol. [(E)-tetradec-11-enyl] acetate has a fruity and slightly floral odor and is often used in the fragrance industry to add a sweet, fruity note to perfumes and other scented products. It is also found in some natural sources such as jasmine and citrus fruits. Additionally, it can be used as a flavoring agent in food products or as a pheromone in insect control. Overall, [(E)-tetradec-11-enyl] acetate is a versatile compound with various applications in the fragrance, food, and agricultural industries.

Upstream product

• 108-24-7 acetic anhydride 
• 19101-00-9 (11?hydroxyundecyl)triphenylphosphonium bromide 
• 123-38-6 propionaldehyde 
• 50405-39-5 1-bromobut-1-yne 
• 50816-18-7 9-decen-1-yl acetate 
• 127-08-2 potassium acetate 
• 83748-51-0 1-chloro-11E-tetradecene 
• 127-09-3 sodium acetate 
• 133074-64-3 Z/E-11-tetradecenyl bromide 
• 35153-18-5 (E)-11-tetradecen-1-ol 
• 925-90-6 ethylmagnesium bromide 
• 98752-59-1 (E)-2-(8-phenylthiododec-11-enyloxy)tetrahydro-2H-pyran 
• 114052-40-3 Δ¹¹-tetradecenol 
• 62466-69-7 5-Bromo-1-(1'-ethoxyethoxy)pentane 

Relevant articles and documents

SYNTHESIS OF PHEROMONE DERIVATIVES VIA Z-SELECTIVE OLEFIN METATHESIS

Disclosed herein are methods for synthesizing fatty olefin metathesis products of high Z-isomeric purity from olefin feedstocks of low Z-isomeric purity. The methods include contacting a contacting an olefin metathesis reaction partner, such as acylated alkenol or an alkenal acetal, with an internal olefin in the presence of a Z-selective metathesis catalyst to form the fatty olefin metathesis product. In various embodiments, the fatty olefin metathesis products are insect pheromones. Pheromone compositions and methods of using them are also described.

SYNTHESIS OF PHEROMONES AND RELATED MATERIALS VIA OLEFIN METATHESIS

Methods for preparation of olefins, including 8- and 11-unsaturated monoenes and polyenes, via transition metathesis-based synthetic routes are described. Metathesis reactions in the methods are catalyzed by transition metal catalysts including tungsten-, molybdenum-, and ruthenium-based catalysts. The olefins include insect pheromones useful in a number of agricultural applications.

SYNTHESIS OF Z-OLEFIN-CONTAINING LEPIDOPTERAN INSECT PHEROMONES

The present invention is directed to methods of synthesizing insect pheromones, particularly lepidopteran insect pheromones, their precursors and derivatives from inexpensive, readily available starting materials using olefin metathesis catalysis.