393177-40-7

Upstream product

• 209069-55-6 5-(tert-Butyl-dimethyl-silanyloxy)-2,6,6-trimethyl-cyclohex-1-enecarbaldehyde 
• 37715-31-4 (E)-5-(3,3-dimethyloxiran-2-yl)-3-methylpent-2-enyl acetate 
• 66465-72-3 5-hydroxy-2,6,6-trimethylcyclohex-1-enecarbaldehyde 

Downstream Products

• 150966-63-5 3-(tert-butyldimethylsiloxymethyl)-2,2,4-trimethyl-cyclohex-3-ene-1-one 

Relevant academic research and scientific papers

A novel approach to the Taxol A-ring synthetic equivalents

A novel short approach to the A-ring synthetic equivalents of Taxol was described. Oxabicyclic ketone 3 served as a versatile template for selective functionalization leading to oxabicyclic vinylic ether 6 in two steps, which was hydrolyzed under mild aci

Stereo- and regio-selective Ti-mediated radical cyclization of epoxy-alkenes: Synthesis of the A and C ring synthons of paclitaxel

We have developed a practical synthetic route for the A and C rings of paclitaxel. The key reaction is a Ti-mediated radical cyclization of an epoxyalkene.