3938-14-5Relevant academic research and scientific papers
Oxidation of (-)-2-bromo-3-hydroxy-N-methyl-6-oxomorphinan with Fremy's salt. An unprecedented 2,4-shift of the bromo substituent. (Chemistry of opium alkaloids, Part XIII)
Olieman, C.,Maat, L.,Beyerman, H. C.
, p. 169 - 175 (2007/10/02)
(-)-3-hydroxy-N-methyl-6-oxomorphinan (6a) and its (-)-2-bromo derivative (6b) were converted into (-)-2,3-dihydroxy-N-methyl-6-oxomorphinan (8a) and its (-)-4-bromo derivative (8b), respectively, by oxidation with Fremy's salt to the ortho-quinones, foll
