395066-95-2Relevant academic research and scientific papers
Umpolung of the reactivity of allylsilanes. Palladium(II) catalyzed cyclization of allylsilyl alcohols: A new route to substituted 2- vinyltetrahydrofurans
MacSári, István,Szabó, Kálmán J.
, p. 1119 - 1122 (2000)
Functionalized allylsilanes 1-4 undergo palladium(II) catalyzed ring closure to afford 4- and/or 5-substituted 2-vinyltetrahydrofurans (5-8) under mild conditions. The catalytic reactions proceed through (η3- allyl)palladium intermediates forme
Palladium-catalyzed cyclization of allylsilanes with nucleophilic displacement of the silyl group
Macsari, Istvan,Szabo, Kalman J.
, p. 4097 - 4106 (2007/10/03)
Allylsilanes containing hydroxy or tosylamide groups undergo palladium(II)-catalyzed cyclization to afford derivatives of tetrahydrofuran, piperidine, and pyrrolidine. This catalytic reaction proceeds through an (η3-allyl)palladium intermediate
