39563-54-7

Basic information

• Product Name: 2-bromoundecane
• Synonyms: 2-bromoundecane;Einecs 254-514-7
• CAS NO: 39563-54-7
• Molecular Formula: C₁₁H₂₃Br
• Molecular Weight: 235.20432
• EINECS: 254-514-7
• Mol File: 39563-54-7.mol
• Article Data: 4

Chemical Properties

• Boiling Point: 252.6°Cat760mmHg
• Flash Point: 77.3°C
• Appearance: /
• Density: 1.051g/cm³
• Vapor Pressure: 0.0305mmHg at 25°C
• Refractive Index: 1.455
• CAS DataBase Reference: 2-bromoundecane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-bromoundecane(39563-54-7)
• EPA Substance Registry System: 2-bromoundecane(39563-54-7)

Safety Data

• Hazardous Substances Data: 39563-54-7(Hazardous Substances Data)

Usage

Synthesis Reference(s)

The Journal of Organic Chemistry, 46, p. 3909, 1981 DOI: 10.1021/jo00332a030

InChI:InChI=1/C11H23Br/c1-3-4-5-6-7-8-9-10-11(2)12/h11H,3-10H2,1-2H3

Upstream product

• 74036-98-9 1,10-dibromoundecane 
• 58856-08-9 2-methylselenoundecane 
• 112-31-2 caprinaldehyde 
• 112-12-9 methyl nonyl ketone 
• 68141-17-3 2-methylundecanal dimethyl acetal 
• 286408-72-8 2,3-dimethyl-2-(1-methoxy-2-methylundecyl)peroxybut-3-ene 
• 61539-80-8 (undecane-2-seleninyl)-benzene 
• 58856-10-3 2-methaneseleninyl-undecane 
• 821-95-4 1-undecene 
• 1653-30-1 undecan-2-ol 

Downstream Products

• 6345-92-2 (1-methyl-decyl)-malonic acid diethyl ester 
• 928-23-4 2--ethanthioschwefelsaeure 
• 124-18-5 decane 
• 1120-21-4 n-Undecane 
• 13490-36-3 3-methyldodecanoic acid 

Relevant articles and documents

Iron(II) and Copper(I) Control the Total Regioselectivity in the Hydrobromination of Alkenes

A new method that allows the complete control of the regioselectivity of the hydrobromination reaction of alkenes is described. Herein, we report a radical procedure with TMSBr and oxygen as common reagents, where the formation of the anti-Markovnikov product occurs in the presence of parts per million amounts of the Cu(I) species and the formation of the Markovnikov product occurs in the presence of 30 mol % iron(II) bromide. Density functional theory calculations combined with Fukui's radical susceptibilities support the obtained results.

Intramolecular homolytic displacements. 30. Functional decarbonylative transformations of aldehydes via homolytically induced decomposition of unsaturated peroxyacetals

Homolytically induced decompositions of unsaturated peroxyacetals, synthesized from aldehydes, gave alkoxyalkoxyl radicals that yielded alkyl radicals by rapid β-scission. The latter radicals could react with several types of "transfer agents" to smoothly bring about homolytic decarbonylative functional group transformations of aldehydes into halides, hydrocarbons, xanthates, alkanenitriles, 2-alkyl-3-chloromaleic anhydrides, 1-phenylalk-1-ynes, and ethyl 2-alkylpropenoates.