395666-12-3

Upstream product

• 395666-01-0 4-O-tert-butyldiphenylsilyl-3-deoxy-1,2-O-isopropylidene-β-D-erythro-hexulopyranose 
• 395666-05-4 4-O-tert-butyldiphenylsilyl-3,5-dideoxy-1,2-O-isopropylidene-5-C-methylene-β-D-glycero-hexulopyranose 
• 395666-04-3 (5R,9S)-9-(tert-Butyl-diphenyl-silanyloxy)-2,2-dimethyl-1,3,6-trioxa-spiro[4.5]decan-8-one 
• 58479-61-1 tert-butylchlorodiphenylsilane 
• 98-88-4 benzoyl chloride 
• 395666-07-6 4-O-tert-butyldiphenylsilyl-3,5-dideoxy-5-C-hydroxymethyl-1,2-O-isopropylidene-α-L-threo-hexulopyranose 

Downstream Products

• 395666-14-5 5-C-benzoyloxymethyl-3,5-dideoxy-1,2-O-isopropylidene-4-O-(3,5-dinitrobenzoyl)-α-L-erythro-hexulopyranose 
• 395666-13-4 5-C-benzoyloxymethyl-3,5-dideoxy-1,2-O-isopropylidene-α-L-threo-hexulopyranose 

Relevant academic research and scientific papers

Synthesis of branched-chain hexulose derivatives as model for the synthesis of talaromycins

The synthesis of 3,5-dideoxy-1,2-O-isopropylidene-5-C-hydroxymethyl-β-D-erythro- (1) and α-L-threo-hexulopyranose (2) from 3-deoxy-1,2-O-isopropylidene-β-D-erythro-hexulopyranose (5) from D-fructose is described, as well as their respective transformation