396131-50-3Relevant academic research and scientific papers
Transition metal-catalysed acylation of α,β-unsaturated carbonyl compounds with acylstannanes
Shirakawa,Yamamoto,Nakao,Tsuchimoto,Hiyama
, p. 1926 - 1927 (2007/10/03)
Acylstannanes were found to add to such α,β-unsaturated carbonyl compounds as enones or ynoates in the presence of a nickel or palladium catalyst to give 2-stannyl-4-oxoalk-2-enoates or 1,4-diketones, whereas the three component coupling between acylstannanes, enones and aldehydes provided 2-hydroxymethyl 1,4-diketones.
