39615-42-4Relevant academic research and scientific papers
UV light-mediated difunctionalization of alkenes with CF3SO2Na: Synthesis of trifluoromethyl phenanthrene and anthrone derivatives
Li, Bing,Fan, Dan,Yang, Chao,Xia, Wujiong
, p. 5293 - 5297 (2016)
A metal-free and cost-effective protocol for UV light-mediated difunctionalization of alkenes with CF3SO2Na was developed. This strategy realized the direct formation of Csp3-CF3 and C-C bonds through a proposed
Further Insight into the Photochemical Behavior of Aromatic γ,δ-Epoxy Ketones: A New Approach for Synthesis of 4-Methyleneisochromanols
Li, Bing,Yang, Chao,Xia, Weitao,Xia, Wujiong
supporting information, p. 1997 - 2000 (2015/09/01)
The photochemical behavior of methyl-substituted aromatic γ,δ-epoxy ketones was investigated by irradiation with a 500 W high-pressure mercury lamp in benzene which led to the formation of 4-methyleneisochromanols through δ-hydrogen abstraction-epoxy rear
Photochemical studies on aromatic γ,δ-epoxy ketones: Efficient synthesis of benzocyclobutanones and indanones
Shao, Yutian,Yang, Chao,Gui, Weijun,Liu, Yang,Xia, Wujiong
supporting information; experimental part, p. 3560 - 3562 (2012/06/04)
Irradiation of terminal aromatic γ,δ-epoxy ketones with a 450 W UV lamp led to Norrish type II cyclization/semi-pinacol rearrangement cascade reaction which formed the benzocyclobutanones containing a full-carbon quaternary center, whereas irradiation of substituted aromatic γ,δ-epoxy ketones led to the indanones through a photochemical epoxy rearrangement and 1,5-biradicals cyclization tandem reaction.
