39669-92-6

Usage

Uses

Used in Chemical Synthesis:
Tetradeca-1,3-diene is used as a chemical intermediate for the synthesis of various organic compounds. Its presence of double bonds allows for a range of reactions that can lead to the formation of different molecules, making it a valuable component in the production of pharmaceuticals, agrochemicals, and other specialty chemicals.
Used in Material Science:
In the field of material science, tetradeca-1,3-diene is used as a precursor for the development of new materials with specific properties. Its potential to undergo polymerization can lead to the creation of polymers with unique characteristics, such as enhanced strength, flexibility, or thermal stability, which can be utilized in various industries.
Used in Research and Development:
Tetradeca-1,3-diene serves as a model compound for studying the properties and reactivity of alkenes. It is used in academic and industrial research to understand the mechanisms of various chemical reactions, such as oxidation and halogenation, which can provide insights into the development of new synthetic methods and applications.
Used in Environmental Applications:
Tetradeca-1,3-diene may also find use in environmental applications, such as in the development of biodegradable plastics or as a component in the synthesis of compounds that can help in the remediation of environmental pollutants. Its potential to be synthesized from renewable sources or to be used in processes that reduce environmental impact makes it an interesting candidate for green chemistry initiatives.

InChI:InChI=1/C14H26/c1-3-5-7-9-11-13-14-12-10-8-6-4-2/h3,5,7H,1,4,6,8-14H2,2H3

Upstream product

• 112-44-7 undecylaldehyde 
• 762-72-1 allyl-trimethyl-silane 
• 1515-76-0 1-acetoxy-1,3-butadiene 
• 17049-50-2 n-decyl magnesium bromide 
• 91899-45-5 1-chloro-trans-2-tetradecene 
• 1560-54-9 allyltriphenylphosphonium bromide 
• 15935-94-1 allylidenetriphenylphosphorane 

Relevant academic research and scientific papers

CONJUGATED DIENE PRODUCTION METHOD

PROBLEM TO BE SOLVED: To provide a novel conjugated diene production method. SOLUTION: A method of producing a conjugated diene represented by the specified general formula (2) is characterized by reacting 1-acyloxy-1,3-alkadiene represented by the specified general formula (1) with a Grignard reagent represented by R6-Mg-X in the presence of an iron catalyst. SELECTED DRAWING: None COPYRIGHT: (C)2018,JPO&INPIT

The fate of bis(η3-allyl)palladium complexes in the presence of aldehydes (or imines) and allylic chlorides: Stille coupling versus allylation of aldehydes (or imines)

The mere presence or absence of PPh3 suffices to control the reactivity of bis(η3-allyl)palladium complexes. In the absence of PPh3 they undergo chemoselective allylic addition to aldehydes or imines, even in the presence of allylic chlorides, whereas in the presence of PPh3 the Stille coupling reaction takes place chemoselectively, even when aldehydes or imines are also present (see scheme).

A simplified Wittig synthesis using a solid/liquid transfer process. IX. Selectivity of the condensation reaction of moderated ylides with aldehydes

Conjugated dienes are obtained selectively and with high yields using aldehydes of various structures. The synthesis is made in a two-phase medium, i.e. solid/liquid medium.

New and Highly (E)-Selective Synthesis of Terminal 1,3-Diene via Three-Carbon Elongation of Aldehyde

A new synthetic method of 1,3-diene by three-carbon elongation of aldehyde is described. 3-Trimethylsilyl-1-propenylzirconocene chloride (2), generated from 3-trimethylsilyl-1-propyne (1) and Cp2Zr(H)Cl, reacts with aldehyde in the presence of catalytic AgClO4 and subsequent one-pot 1,4-elimination affords 1,3-dienes in high yields with excellent (E)-selectivities.