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[Ru(II)Cl2(triphenylphosphine)(η6-benzene)] is a coordination complex consisting of a ruthenium (Ru) center in the +2 oxidation state, two chloride (Cl) ligands, one triphenylphosphine (PPh3) ligand, and one η6-benzene ligand. The complex has a square planar geometry around the ruthenium atom, with the two chloride ligands occupying two of the coordination sites, the triphenylphosphine ligand occupying another, and the η6-benzene ligand completing the coordination sphere by binding through all six of its carbon atoms. This complex is of interest in various fields, including catalysis and materials science, due to its unique electronic properties and potential applications in homogeneous catalysis and as a precursor for the synthesis of other ruthenium-containing compounds.

39732-57-5

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39732-57-5 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 39732-57-5 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,9,7,3 and 2 respectively; the second part has 2 digits, 5 and 7 respectively.
Calculate Digit Verification of CAS Registry Number 39732-57:
(7*3)+(6*9)+(5*7)+(4*3)+(3*2)+(2*5)+(1*7)=145
145 % 10 = 5
So 39732-57-5 is a valid CAS Registry Number.

39732-57-5Relevant academic research and scientific papers

Acceptorless and Base-free Dehydrogenation of Cyanohydrin with (η6-Arene)halide(Bidentate Phosphine)ruthenium(II) Complex

Kim, Kicheol,Moeljadi, Adhitya Mangala Putra,Hirao, Hajime,Hong, Soon Hyeok

supporting information, p. 3292 - 3298 (2017/09/06)

Ruthenium-catalyzed dehydrogenation of cyanohydrins under acceptorless and base-free conditions was demonstrated for the first time in the synthesis of acyl cyanide. As opposed to the thermodynamically preferred elimination of hydrogen cyanide, the dehydrogenation of cyanohydrins could be kinetically controlled with ruthenium (II) bidentate phosphine complexes. The effects of the arene, phosphine ligands and counter anions were investigated in regard to catalytic activity and selectivity. Selective dehydrogenation can occur via β-hydride elimination with the experimentally observed [(alkoxide)Ru] complex. (Figure presented.).

New ruthenium(II)-letrozole complexes as anticancer therapeutics

Castonguay, Annie,Doucet, Cédric,Juhas, Michal,Maysinger, Dusica

, p. 8799 - 8806 (2013/01/15)

Novel ruthenium-letrozole complexes have been prepared, and cell viability of two human cancer cell types (breast and glioblastoma) was determined. Some ruthenium compounds are known for their cytotoxicity to cancer cells, whereas letrozole is an aromatas

Hydrogen generation: Catalytic acceleration and control by light

Loges, Bjoern,Boddien, Albert,Junge, Henrik,Noyes, James R.,Baumann, Wolfgang,Beller, Matthias

, p. 4185 - 4187 (2011/03/19)

The ruthenium-catalyzed generation of hydrogen from formic acid is significantly accelerated by light.

Arene(phosphane)metal Complexes, I. The Precursors for the Synthesis of the Metal Bases ArM(PR3)2 and ArM(PR3)L (M = Ru, Os)

Werner, Helmut,Werner, Rainer

, p. 3766 - 3780 (2007/10/02)

The halide-bridged compounds 2 (Ar = C6H6, p-cymene, C6Me6; X = Cl, and Ar = C6H6; X = I) and 2 react with Lewis bases L, e.g.CO, tertiary phosphanes, or trimethyl phosphite, to give the mononuclear complexes ArMX2(L) (1 - 9).From these

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