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(1S*,2S*)-N,N-diisopropyl-2-phenylcyclopropane-1-carboxamide is a chiral organic compound with the molecular formula C18H25NO. It features a cyclopropane ring, which is a three-membered carbon ring, and a phenyl group attached to the cyclopropane. The compound has two isopropyl groups (C3H7) attached to the nitrogen atom, and a carboxamide group (-CO-NH2) at the end. The stereochemistry of the compound is specified by the (1S*,2S*) notation, indicating that both the first and second carbon atoms in the cyclopropane ring have the S configuration. (1S*,2S*)-N,N-diisopropyl-2-phenylcyclopropane-1-carboxamide is of interest in the field of organic chemistry, particularly in the study of chiral molecules and their applications in pharmaceuticals and other industries.

3977-96-6

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3977-96-6 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 3977-96-6 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,9,7 and 7 respectively; the second part has 2 digits, 9 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 3977-96:
(6*3)+(5*9)+(4*7)+(3*7)+(2*9)+(1*6)=136
136 % 10 = 6
So 3977-96-6 is a valid CAS Registry Number.

3977-96-6Downstream Products

3977-96-6Relevant academic research and scientific papers

Stereospecific cyclopropanation of highly substituted C-C double bonds promoted by CrCl2. Stereoselective synthesis of cyclopropanecarboxamides and cyclopropyl ketones

Concellon, Jose M.,Rodriguez-Solla, Humberto,Mejica, Carmen,Blanco, Elena G.

, p. 2981 - 2984 (2008/02/09)

We describe herein a CrCl2-promoted cyclopropanation of α,β-unsaturated amides. This reaction can be carried out on (E)- or (2)-α,β-enamides in which the C-C double bond is di-, tri-, or tetrasubstituted. In all cases the process is completely stereospecific and only a single diastereoisomer is obtained. In addition, cyclopropyl ketones were readily prepared by reaction of the cyclopropanecarboxamides (derived from morpholine) obtained with a range of organolithium compounds. A mechanism has been proposed to explain the cyclopropanation reaction.

ENHANCEMENT OF STEREOSELECTIVITY IN CATALYTIC CYCLOPROPANATION REACTIONS

Doyle, Michael P.,Loh, Kuo-Liang,DeVries, Keith M.,Chinn, Mitchell S.

, p. 833 - 836 (2007/10/02)

Significat enhancement of trans(anti) stereoselectivity is achieved in rhodium(II) acetamide catalyzed cyclopropanation reactions of 2,3,4-trimethyl-3-pentyl diazoacetate (ODA) and diazoacetamides.

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