39778-92-2Relevant academic research and scientific papers
Addition of Organometallic Reagents to Cyclooctenyl Phenyl Sulfones
Hardinger, Steven A.,Fuchs, P. L.
, p. 2739 - 2749 (1987)
A series of cyclooctenyl and cyclooctadienyl phenyl sulfones were prepared and exposed to various organometallic reagents.The regio- and stereochemical results of these reactions are outlined below.The cuprate-induced reduction of epoxy vinyl sulfones 17 and 29 was explored; a mechanism involving two one-electron transfers was implicated.
SYNTHESIS OF β-FLUOROALKYL PHENYL (OR METHYL) THIOETHERS BY SULFUR-ASSISTED HALOGEN EXCHANGE WITH TRIETHYLAMINE TRIS-HYDROFLUORIDE
Saluzzo, C.,Alvernhe, G.,Anker, D.,Haufe, G.
, p. 467 - 479 (2007/10/02)
The exchange of chlorine in β-chloroalkyl phenyl (or methyl) thioethers by fluorine, with anchimeric assistance of sulfur, is very easily realized with the almost neutral fluorinating reagent, Et3N*3HF.The 'one-pot' reactions of alkenes with sulfenyl chlo
