Journal of Organic Chemistry p. 2739 - 2749 (1987)
Update date:2022-07-31
Topics:
Hardinger, Steven A.
Fuchs, P. L.
A series of cyclooctenyl and cyclooctadienyl phenyl sulfones were prepared and exposed to various organometallic reagents.The regio- and stereochemical results of these reactions are outlined below.The cuprate-induced reduction of epoxy vinyl sulfones 17 and 29 was explored; a mechanism involving two one-electron transfers was implicated.
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