Addition of Organometallic Reagents to Cyclooctenyl Phenyl Sulfones

DOI: 10.1021/jo00389a019

Source and publish data:

Journal of Organic Chemistry p. 2739 - 2749 (1987)

Update date:2022-07-31

Topics:

Authors:

Hardinger, Steven A.

Fuchs, P. L.

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Article abstract of DOI:10.1021/jo00389a019

A series of cyclooctenyl and cyclooctadienyl phenyl sulfones were prepared and exposed to various organometallic reagents.The regio- and stereochemical results of these reactions are outlined below.The cuprate-induced reduction of epoxy vinyl sulfones 17 and 29 was explored; a mechanism involving two one-electron transfers was implicated.

Full text of DOI:10.1021/jo00389a019

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