39786-24-8Relevant academic research and scientific papers
Cu(BTC)-MOF catalyzed multicomponent reaction to construct 1,4-disubstituted-1,2,3-triazoles
Jia, Xiangru,Xu, Guangli,Du, Zhengyin,Fu, Ying
, p. 515 - 519 (2018/06/26)
Cu(BTC)-MOF catalyzed one-pot, three-component reaction of terminal alkynes, halides and sodium azide to form 1,4-disubstituted-1,2,3-triazoles was investigated. It was conducted in methanol under room temperature with good to excellent product yields. Th
Nano-copper catalyzed three-component reaction to construct 1,4-substituted 1,2,3-triazoles
Huang, Lina,Liu, Wei,Wu, Juncheng,Fu, Ying,Wang, Kehu,Huo, Congde,Du, Zhengyin
supporting information, p. 2312 - 2316 (2014/04/17)
Three-component reaction of alkyl halides, sodium azide with terminal alkynes can be catalyzed by nano-copper particles under ambient conditions. A series of 1,4-disubstituted-1,2,3-triazoles were obtained regioselectively by this one-pot strategy. Nano c
The effects of ionic liquids on azide-alkyne cycloaddition reactions
George, Stephen R. D.,Edwards, Gavin L.,Harper, Jason B.
supporting information; experimental part, p. 5354 - 5358 (2011/01/12)
The effect of a series of ionic liquids on the regioselectivity of the azide-alkyne cycloaddition process was investigated, demonstrating an increased selectivity for the least hindered triazole. The effects of an ionic liquid on the activation parameters for the process were determined and found to be intermediate between coordinating and non-coordinating salts. The importance of knowing the water content of the system is demonstrated by marked changes in the activation parameters in the presence of small concentrations of water.
