13686-33-4 Usage
General Description
Tert-butyl azide is a chemical compound with the formula (CH3)3CN3. It is a highly reactive and explosive organic azide that is commonly used in organic synthesis and chemical research. Tert-butyl azide is known for its ability to undergo diazo transfer and participate in the Huisgen cycloaddition reactions, as well as its use in the preparation of a variety of azido compounds. Due to its explosive nature and potential hazards, tert-butyl azide should be handled with extreme caution and only in a properly equipped laboratory by trained personnel.
Check Digit Verification of cas no
The CAS Registry Mumber 13686-33-4 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,6,8 and 6 respectively; the second part has 2 digits, 3 and 3 respectively.
Calculate Digit Verification of CAS Registry Number 13686-33:
(7*1)+(6*3)+(5*6)+(4*8)+(3*6)+(2*3)+(1*3)=114
114 % 10 = 4
So 13686-33-4 is a valid CAS Registry Number.
InChI:InChI=1/C4H9N3/c1-4(2,3)6-7-5/h1-3H3
13686-33-4Relevant articles and documents
tert-Butyl Cation Formation in the Hydrolysis of 2-Methyl-2-propanesulfonyl Chloride, the Simplest Tertiary Alkanesulfonyl Chloride
King, James F.,Lam, Joe Y. L.,Dave, Vinod
, p. 2831 - 2834 (2007/10/02)
Evidence is presented that only significant reaction of 2-methyl-2-propanesulfonyl chloride (1) (a) in water over the pH range 3.5-13.0 or (b) in methanol-chloroform-d is an ionization to the tert-butyl cation (2) and the chlorosulfite anion (ClSO2(-)), followed by further reactions of these species.The organic products include isobutylene (3), tert-butyl chloride (4a), tert-butyl alcohol (4b), and, at high pH, 2-methyl-2-propanesulfinate anion (6) and small amounts of 2-methyl-2-propanesulfonate anion (5).In the presence of barium chloride the rate of hydrolysis of 1 is constant over the pH range 3.5-12.0.
