397872-83-2

Upstream product

• 111-29-5 1 ,5-pentanediol 
• 83067-20-3 5-(tert-butyldimethyl-silyloxy)pentan-1-ol 
• 87184-80-3 5-tert-butyldimethylsilyloxypentanal 
• 220384-66-7 7-[tert-butyl(dimethyl)silyl]oxy-1-(trimethylsilyl)hept-1-yn-3-one 
• 14194-86-6 5-(2-tetrahydropyranyloxy)pentanal 
• 76102-74-4 5-(tetrahydro-2H-pyran-2-yloxy)pentan-1-ol 
• 397872-82-1 1-(tert-butyl-dimethyl-silyloxy)-5-(tert-butyl-diphenyl-silyloxy)-7-(trimethyl-silyl)-hept-6-yne 
• 665053-46-3 7-(tetrahydro-pyran-2-yloxy)-1-trimethylsilanyl-hept-1-yn-3-ol 

Downstream Products

• 397872-84-3 5-(tert-butyl-diphenyl-silanyloxy)-hept-6-yn-1-ol 
• 665053-51-0 7-(tert-butyl-diphenyl-silanyloxy)-9-trimethylsilanyl-non-2-en-8-yn-1-ol 
• 665053-54-3 {(2S,3S)-3-[4-(tert-Butyl-diphenyl-silanyloxy)-6-trimethylsilanyl-hex-5-ynyl]-oxiranyl}-methanol 
• 397872-67-2 7-(tert-butyl-diphenyl-silanyloxy)-non-2-en-8-ynoic acid methyl ester 

Relevant academic research and scientific papers

Stereoselective Intramolecular Nicholas Reaction Using Epoxides as Nucleophiles

(Matrix presented) The intramolecular nucleophilic attack of the epoxides on the exo-Co2(CO)6-propargylic cations provided cyclic ethers in good yields. The use of substrates with stereochemically defined oxiranes provided polysubsti

Syntheses of anolignans A and B using ruthenium-catalyzed cross-enyne metathesis

Anolignans A and B were synthesized using ruthenium-catalyzed cross-enyne metathesis as the key steps. The 1,3-diene moieties of these natural products were constructed by the introduction of the methylene parts of ethylene into alkyne using Grubbs' catalyst.