398142-27-3Relevant academic research and scientific papers
Formal radical cyclization onto benzene rings - A general method proceeding via cross-conjugated dienones
Clive, Derrick L. J.,Fletcher, Stephen P.,Zhu, Mingzhao
, p. 526 - 527 (2003)
Cross-conjugated dienones of type 5 (X = I), which are readily available from phenols, undergo radical cyclization (5 → 6 → 7), and the products are easily aromatized (7 → 8), giving substances that are formally derived by radical cyclization onto a benze
Formal Radical Cyclization onto Benzene Rings: A General Method and Its Use in the Synthesis of ent-Nocardione A
Clive, Derrick L. J.,Fletcher, Stephen P.,Liu, Dazhan
, p. 3282 - 3293 (2007/10/03)
An indirect method is described for effecting radical cyclization onto a benzene ring. Cross-conjugated dienones 6, which are readily prepared from phenols, undergo radical cyclization (6 → 7 → 8), and the products (8) are easily aromatized. The method ha
A highly enantioselective intramolecular heck reaction with a monodentate ligand
Imbos, Rosalinde,Minnaard, Adriaan J.,Feringa, Ben L.
, p. 184 - 185 (2007/10/03)
An efficient enantioselective intramolecular Heck reaction of cyclohexadienones, using readily available and modular TADDOL-based mono- and bidentate phosphoramidites as chiral ligands and not requiring any additives, has been developed. Excellent enantio
