39830-94-9Relevant academic research and scientific papers
Photophthalimidation of unactivated double bonds. Synthesis of protected phenethylamines
Suau, Rafael,Garcia-Segura, Rafael,Sanchez, Cristobal,Pedraza, Ana Maria
, p. 2007 - 2010 (1999)
At low hydroxide ion concentrations, the photoaddition of phthalimide to cyclohexene, indene or styrene derivatives takes place. The cation radical obtained in the electron transfer from the alkene to excited phthalimide is trapped by phthalimide anion. At high hydroxide ion concentrations concerted [2+2] cycloaddition occurs that yields benzazepinediones, whatever the ionization potential of the alkene. The most suitable reaction conditions can be inferred from the observed fluorescence of phthalimide anion.
Photocycloaddition of phthalimide anion to alkenes - A highly efficient, convergent method for [2]benzazepine synthesis
Suau, Rafael,Sanchez-Sanchez, Cristobal,Garcia-Segura, Rafael,Perez-Inestrosa, Ezequiel
, p. 1903 - 1911 (2007/10/03)
The excited state of phthalimide anion adds to cyclic, acyclic and aryl-conjugated alkenes in an efficient and regioselective manner to form [2]benzazepine-1,5-diones, substituted at positions 3 and/or 4. The reaction is independent of the ionization pote
PHOTOCHEMICAL ADDITION OF ALKENES AND ALCOHOLS TO SODIUM PHTHALIMIDE
Suarez, R. Suau,Segura, R. Garcia
, p. 1071 - 1074 (2007/10/02)
The results of the photochemical reaction between sodium phthalimide and alkenes (1-hexene and cyclohexene) or alcohols (methanol and tert-butanol) are described.
