39870-00-3Relevant academic research and scientific papers
Deoxygenation of Nitrous Oxide and Nitro Compounds Using Bis(N-Heterocyclic Silylene)Amido Iron Complexes as Catalysts
Chen, Xi,Driess, Matthias,Du, Shaozhi,Mo, Zhenbo,Wang, Hao
, (2021/12/03)
Herein, we report the efficient degradation of N2O with a well-defined bis(silylene)amido iron complex as catalyst. The deoxygenation of N2O using the iron silanone complex 4 as a catalyst and pinacolborane (HBpin) as a sacrificial reagent proceeds smoothly at 50 °C to form N2, H2, and (pinB)2O. Mechanistic studies suggest that the iron–silicon cooperativity is the key to this catalytic transformation, which involves N2O activation, H atom transfer, H2 release and oxygenation of the boron sites. This approach has been further developed to enable catalytic reductions of nitro compounds, producing amino-boranes with good functional-group tolerance and excellent chemoselectivity.
Syntheses, structures and characterizations of two organoimido derivatives of POMs containing sulfide groups
Guo, Hui,Li, Shang-Ze,Xiong, Xin-Xing,Li, Di,Liu, Zi-Yang,Wang, Long-Sheng,Wu, Ping-Fan
, p. 1 - 6 (2015/04/14)
Two remote methylthio group functionalized organoimido derivatives of hexamolybdate, (Bu4N)2[Mo6O18(NC6H4-SCH3-p)] (1) and (Bu4N)2[Mo6O18/s
