399042-68-3Relevant academic research and scientific papers
Construction of supported organometallics using cycloplatinated arylamine ligands
Meijer, Michel D.,Kleij, Arjan W.,Scott Williams,Ellis, Dianne,Lutz, Martin,Spek, Anthony L.,Van Klink, Gerard P.M.,Van Koten, Gerard
, p. 264 - 271 (2008/10/08)
The preparation of ortho-chelating aminoaryl ligands ([C6H3(CH2NMe2)-2-R-4]-, abbreviated as C,N) containing a pendant hydroxymethyl group is described. These ligands have been cycloplatinated with cis-PtCl2(DMSO)2, yielding the corresponding C,N-platinum(II) complexes. The pendant hydroxymethyl substituent is a versatile group for attachment of the organometallic moiety to macromolecules, which has been demonstrated by attaching the C,N-platinum complexes to a dendritic wedge and to C60.
