39910-24-2

Basic information

• Product Name: ethyl-3-hydroxy-2-diazo-3-(4-methoxyphenyl)-propanoate
• Synonyms: ethyl-3-hydroxy-2-diazo-3-(4-methoxyphenyl)-propanoate
• CAS NO: 39910-24-2
• Molecular Weight: 250.254
• Mol File: 39910-24-2.mol
• Article Data: 19

Chemical Properties

• CAS DataBase Reference: ethyl-3-hydroxy-2-diazo-3-(4-methoxyphenyl)-propanoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl-3-hydroxy-2-diazo-3-(4-methoxyphenyl)-propanoate(39910-24-2)
• EPA Substance Registry System: ethyl-3-hydroxy-2-diazo-3-(4-methoxyphenyl)-propanoate(39910-24-2)

Safety Data

• Hazardous Substances Data: 39910-24-2(Hazardous Substances Data)

Upstream product

• 623-73-4 diazoacetic acid ethyl ester 
• 123-11-5 4-methoxy-benzaldehyde 
• 17145-48-1 ethyl 2-diazo-2-(trimethylsilyl)acetate 
• 141-97-9 ethyl acetoacetate 

Downstream Products

• 239094-48-5 C₂₀H₂₁N₃O₇S 
• 1073163-35-5 ethyl 2-diazo-3-(4-methoxyphenyl)-3-oxopropanoate 

Relevant articles and documents

A Conjugate Addition Approach to Diazo-Containing Scaffolds with β Quaternary Centers

Structurally complex diazo-containing scaffolds are formed by conjugate addition to vinyl diazonium salts. The electrophile, a little studied α-diazonium-α,β-unsaturated carbonyl compound, is formed at low temperature under mild conditions by treating β-h

An efficient and convenient aldol addition of acyldiazomethane with aldehydes promoted by MgI2 etherate

The aldol addition of acyldiazomethane with aromatic aldehydes, vinyl aldehyde and aliphatic aldehydes was carried out efficiently in the presence of MgI2 etherate and iPr2EtN (DIPEA) using untreated reagent-grade CH2Cl2 under atmospheric conditions in good to excellent yields. Iodide counterion and a non-coordinating reaction media (i.e. CH2Cl2) are among the critical factors for the unique reactivity of this reaction system.

KF/Nano-clinoptilolite Catalyzed Aldol-Type Reaction of Aldehydes with Ethyl Diazoacetate

Abstract: Potassium fluoride supported on nano-clinoptilolite (KF/CP NPs) was used as an excellent catalytic system for direct aldol-type condensation of aldehydes with ethyl diazoacetate under solvent-less conditions. A variety of α-diazo carbonyl derivatives were prepared in good to excellent yields in short reaction times. Graphical Abstract: [Figure not available: see fulltext.]