39952-43-7

Upstream product

• 1017-60-3 di-p-tolylphosphine 
• 109-72-8 n-butyllithium 

Downstream Products

• 70320-30-8 1,2-bis[di(p-tolyl)phosphino]ethane 
• 874297-60-6 (R,R)-bis[di-(p-tolyl)phosphino]-1,3-dicyclohexylpropane 
• 137467-45-9 1,2-W₂(P(p-tol)2)2(NMe₂)4 
• 137467-46-0 1,2-W₂(mu.-P(p-tol)2)2(NMe₂)4 
• 1163249-32-8 (2-methoxyethyl)di-4-tolylphosphine 
• 1381966-57-9 pentacarbonyl[(diphenylphosphino)(di-p-tolylphosphino)methane]tungsten⁽⁰⁾ 
• 1381966-57-9 pentacarbonyl[(diphenylphosphino)(di-p-tolylphosphino)methane]tungsten⁽⁰⁾ 
• 22031-15-8 1,1,1-tris(di(4-methylphenyl)phosphinomethyl)ethane 
• 1381966-59-1 (diphenylphosphino)(di-p-tolylphosphino)methane 
• 122796-98-9 (R,R)-4,5-Bis-2,2-dimethyl-1,3-dioxolan 

Relevant academic research and scientific papers

Triphos derivatives and diphosphines as ligands in the ruthenium-catalysed alcohol amination with NH3

The ruthenium-triphos and diphosphine-catalysed amination of alcohols with ammonia is reported. Various types of triphos derivatives with electron-donating functional group were synthesized and used as ligands in the Ru-catalysed alcohol amination with NH3. The triphos derivatives are effective for the formation of primary amines. On the other hand, if hemilabile diphosphines as tridentate ligands are used, mixtures of secondary-along with primary amines are obtained. It was found that even simple diphosphines can be used as ligands for the selective formation of the secondary amines. The diphosphine system allows a new entry to the Ru-catalysed formation of secondary amines.

Highly Active and Selective Ethylene Oligomerization Catalyst and Method of Preparing Hexene or Octene Using the Same

This invention relates to a chromium complex compound for selective ethylene oligomerization including a chiral ligand, and to a method of selectively preparing 1-hexene or 1-octene from ethylene using the same.

Convenient methods for the synthesis of a library of hemilabile phosphines

A series of novel functionalized phosphines of hemilabile character, R 2P(CH2)nZ, have been prepared from diarylphosphines using several synthetic methodologies. The synthetic methods include the alkylation of lithium diar