1381966-57-9

Upstream product

• 1381966-62-6 [(bromomethyl)diphenylphosphine]pentacarbonyltungsten⁽⁰⁾ 
• 39952-43-7 lithium di-(p-tolyl)-phosphide 
• 1381966-57-9 pentacarbonyl[(diphenylphosphino)(di-p-tolylphosphino)methane]tungsten⁽⁰⁾ 
• 16969-72-5 W(CO)5(NH₂Ph) 
• 57137-53-8 (chloromethyl)diphenylphosphane 
• 1381966-61-5 [(chloromethyl)diphenylphosphine]pentacarbonyltungsten⁽⁰⁾ 

Downstream Products

• 1381966-57-9 pentacarbonyl[(diphenylphosphino)(di-p-tolylphosphino)methane]tungsten⁽⁰⁾ 

Relevant academic research and scientific papers

Intramolecular exchange of coordinated and dangling phosphine groups in pentacarbonyl[(diphenylphosphino)(di-p-tolylphosphino)methane]tungsten(0)

Equilibrium constants and rates have been determined for the isomerization of the linkage isomers (OC)5W[κ1-PPh 2CH2P(p-tolyl)2] (5) and (OC) 5W[κ1-P(p-tolyl)2CH2PPh 2] (6). It is proposed that this intramolecular exchange involves a nucleophilic attack of the pendant phosphine on a cis carbonyl group, followed by ring opening and a 1,2-shift.