39969-91-0

Upstream product

• 110-89-4 piperidine 
• 93-58-3 benzoic acid methyl ester 
• 100-39-0 benzyl bromide 
• 121-68-6 dithiobenzoic acid 

Downstream Products

• 59937-89-2 tert-Butyl Trithiophenylperformat 
• 85161-06-4 <(thiobenzoyl)thiomethyl>triphenylphosphonium iodide 
• 93752-12-6 2-(hydroxyimino)propyl dithiobenzoate 
• 20968-81-4 In(C₆H₅CS₂)3 
• 922178-04-9 Ga(C₆H₅CS₂)3 
• 313249-98-8 phenyltin tris(benzenecarbodithioate) 
• 120449-41-4 Se-phenyl benzene-carboselenothioate 
• 949-00-8 phenyl dithiobenzoate 
• 18775-06-9 N,N-diethylthiobenzamide 
• 34733-85-2 5-phenyl-1,2,3,4-thiatriazole 
• 85161-00-8 Dithiobenzoic acid (E)-2-(4-nitro-phenyl)-vinyl ester 
• 97346-57-1 C₁₆H₁₄OS₄Te 
• 97364-20-0 C₁₅H₁₂S₄Te 
• 97346-51-5 iodotellurium 4-(methyl)dithiobenzoate 

Relevant academic research and scientific papers

Thioamides via thiatriazolines

A method for thioamide formation from dithioacids and azides is described and a mechanistic framework is presented.

Synthesis and characterization of new 99mTc-radiopharmaceuticals with dithiobenzoate derivatives for the study of septic inflammatory processes

Improved methods for the preparation of 99mTc-radiopharmaceuticals containing dithiobenzoate ligands, in sterile and pyrogen free conditions, are described. These procedures are based on the reaction of these ligands either with [99mTc] pertechnetate in the presence of a strong reducing agent (HCl/ tertiary phosphine, SnCl2·2H2O), or with pre-reduced complexes obtained from different kit formulations. All the preparations led to the high-yield formation of the neutral and lipophilic 99mTc-complex [99mTc][Tc(S3CPh)2 (S2CPh)], which is analogous to the corresponding compounds obtained with rhenium and the long-lived β-emitting isotope technetium- 99 g recently described. HPLC analysis and thin layer chromatography were used to confirm the characterisation of the resulting 99mTc-radiopharmaceutical which was found to be potentially suitable for blood-cell labelling as applied to the diagnosis of inflammatory processes. Copyright

Substituted 1,4,2-Dithiazines: Synthesis by Ring Expansion of 1,3-Dithiolium Cations, Solution Redox Properties and X-Ray Crystal Structures of a Monocyclic and a Bicyclic Derivative

A range of derivatives of the 8 ?-electron 1,4,2-dithiazine system, viz. compounds 11a-d and 19-24, have been synthesized by ring expansion of the corresponding 1,3-dithiolium salts 8a-d and 13-18, respectively, using a mixture of iodine and aqueous ammon

Dithiocarboxylic Acids and Derivatives from Carboxylic Esters and Lactones with the Organoboron Sulfide Reagent (9-BBN)2S

Bis(1,5-cyclooctanediylboryl) sulfide (1) reacts with carboxylic esters to give the dithiocarboxylic 1,5-cyclooctanediylboryl esters 2a-f in high yields (2a: X-ray crystal structure analysis).Methanolysis of 2a-f leads to the dithiocarboxylic acids 5a-f, which form the corresponding piperidinium salts in the presence of piperidine.When cyclic esters (γ-, δ-lactones) are allowed to react with 1, the boryloxy-substituted dithiocarboxylic 1,5-cyclooctanediylboryl esters 3a-c are obtained.Key Words: (9-BBN)2S, reagent / OC-Sulfoborations / 1,2-Eliminations, of R2BOR', (R2B)2O / Dithiocarboxylic 1,5-cyclooctanediylboryl esters / Dithiocarboxylic acids