400076-37-1

Basic information

• Product Name: N-tert-pentanoyloxy-p-chlorobenzamide
• Synonyms: N-tert-pentanoyloxy-p-chlorobenzamide
• CAS NO: 400076-37-1
• Molecular Weight: 255.701
• Mol File: 400076-37-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-tert-pentanoyloxy-p-chlorobenzamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-tert-pentanoyloxy-p-chlorobenzamide(400076-37-1)
• EPA Substance Registry System: N-tert-pentanoyloxy-p-chlorobenzamide(400076-37-1)

Safety Data

• Hazardous Substances Data: 400076-37-1(Hazardous Substances Data)

Upstream product

• 35657-34-2 (O-pivaloylhydroxyl)amine 
• 1613-88-3 4-chloro-N-hydroxybenzamide 
• 3282-30-2 pivaloyl chloride 

Downstream Products

• 1400655-69-7 (Z)-6-chloro-4-(cyclohexylmethylene)-3,4-dihydroisoquinolin-1(2H)-one 
• 24285-73-2 2-(4-chlorophenyl)-5-phenyloxazole 
• 1219-99-4 N,N'-bis(4-chlorophenyl)urea 
• 39814-89-6 N-(p-chlorobenzoyl)triphenylphospha-λ⁵-azene 

Relevant articles and documents

Synthesis of sulfimides and N-Allyl-N-(thio)amides by Ru(II)catalyzed nitrene transfer reactions of N-acyloxyamides

The N-acyloxyamides were employed as effective N-acyl nitrene precursors in reactions with thioethers under the catalysis of a commercially available Ru(II) complex, from which a variety of sulfimides were synthesized efficiently and mildly. If an allyl group is contained in the thioether precursor, the [2,3]-sigmatropic rearrangement of the sulfimide occurs simultaneously and the N-allyl-N-(thio)amides were obtained as the final products. Preliminary mechanistic studies indicated that the Ru-nitrenoid species should be a key intermediate in the transformation.