40078-03-3Relevant articles and documents
On the Mechanism of Graham's Reaction
Moss, Robert A.,Wlostowska, Joanna,Guo, Wenjeng,Fedorynski, Michal,Springer, James P.,Hirshfield, Jordan M.
, p. 5048 - 5050 (1981)
The oxidative cyclization of amidines to 3-chloro-3-substituted diazirines with aqueous sodium hypochlorite proceeds through N-chloro- and N,N'-dichloroamidines; the latter are isolable in certain cases.
Reactivity of 1-chloro-3-phenyldiazirines
Martinu, Tomas,Dailey, William P.
, p. 5012 - 5015 (2007/10/03)
p-Substituted 1-chloro-3-phenyldiazirines (5), the putative intermediates of the reaction of N,N,N′-trichlorobenzamidines (10) with excess of bromide ions, react further to afford mixtures of 3-bromo- (4) and 3-chloro-3-phenyldiazirines (6). The 6:4 ratio