40102-61-2

Basic information

• Product Name: 2-Imidazolidinethione, 4,5-diphenyl-, (4R,5S)-rel-
• CAS NO: 40102-61-2
• Molecular Formula: C15H14N2S
• Molecular Weight: 254.356
• Mol File: 40102-61-2.mol

Chemical Properties

• CAS DataBase Reference: 2-Imidazolidinethione, 4,5-diphenyl-, (4R,5S)-rel-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Imidazolidinethione, 4,5-diphenyl-, (4R,5S)-rel-(40102-61-2)
• EPA Substance Registry System: 2-Imidazolidinethione, 4,5-diphenyl-, (4R,5S)-rel-(40102-61-2)

Safety Data

• Hazardous Substances Data: 40102-61-2(Hazardous Substances Data)

Upstream product

• 75-15-0 carbon disulfide 
• 951-87-1 rac-1,2-diphenylethylene-1,2-diamine 
• 5700-60-7 1,2-Diphenylethylenediamine 

Downstream Products

• 137618-08-7 1,3-di(2-methylbutanoyl)-trans-4,5-diphenylimidazolidine-2-thione 
• 137618-07-6 1,3-di(3-phenylpropionyl)-trans-4,5-diphenylimidazolidine-2-thione 
• 58826-14-5 2-(4-methoxy-benzylidene)-5r,6c-diphenyl-5,6-dihydro-imidazo[2,1-b]thiazol-3-one 
• 74649-27-7 cis-4,5-Diphenyl-2-methylthio-4,5-dihydro-1H-imidazole hydroiodide 
• 137618-10-1 (E)-1-{(4S,5S)-4,5-Diphenyl-3-[(E)-(3-phenyl-acryloyl)]-2-thioxo-imidazolidin-1-yl}-3-phenyl-propenone 
• 137618-05-4 1,3-dipropionyl-trans-4,5-diphenylimidazolidine-2-thione 
• 137638-30-3 1,3-di(2-benzylbutanoyl)-trans-4,5-diphenylimidazolidine-2-thione 
• 1220165-35-4 C₂₈H₃₀N₂OS 
• 1220165-43-4 C₂₅H₂₄N₂OS 
• 1220165-16-1 (2S,4R,5S)-3-[2-(6-methoxynaphthalen-2-yl)propionyl]-4,5-diphenylimidazolidine-2-thione 
• 1220165-39-8 C₂₄H₂₂N₂OS 
• 58826-22-5 2-(benzo[1,3]dioxol-5-yl-p-tolyl-methyl)-5r,6c-diphenyl-5,6-dihydro-imidazo[2,1-b]thiazol-3-one 
• 58826-20-3 2ξ-(4-methoxy-4'-methyl-benzhydryl)-5r,6c-diphenyl-5,6-dihydro-imidazo[2,1-b]thiazol-3-one 
• 58826-19-0 2ξ-(4-methoxy-benzhydryl)-5r,6c-diphenyl-5,6-dihydro-imidazo[2,1-b]thiazol-3-one 

Relevant articles and documents

Bifunctional Chiral Auxiliaries 5: The Synthesis of 1,3-Diacylimidazolidine-2-thiones and 1,3-Diacylimidazolidin-2-ones from 1,2-Diamines

Although 1,2-diamines fail to cyclise with urea, phosgene or 1,1'-carbonyl diimidazole, they react with carbon disulphide to give the corresponding imidazolidine-2-thiones.These undergo clean diacylation to give 1,3-diacylimidazolidine-2-thiones which are

Bifunctional chiral auxiliaries 2: The synthesis of 1,3-diacylimidazolidin-2-ones from 1,2-diamines

The title compounds are readily prepared in three steps via the corresponding 1,3-diacylimidazolidine-2-thiones. The final step involves the novel use of mercury (II) acetate for the conversion of thioureas to ureas.